21 seconds in, to be exact, from 6 meters out, courtesy of Henry's cross. (And yes, I've just quoted myself.)
The UEFA site has commentary, but it's guys in a studio talking about all the matches rather than commentary about a specific match. Right now they're discussing rather Gilberto's goal may surpass the fastest ever in CL history, 20.12 seconds by Del Piero vs. Man U in 1997. No word on how they determine the hundreths of seconds.
5th Rommedahl on the wing, crosses to Kezman, headed wide. After the shock, PSV is coming with all guns blazing.
The early goal seems to have inspired PSV, as Kezman was unmarked from 2 metres out but misses an open header.
12th min Kezman breaks through and for the second time, the ball is in the Arsenal net. Also for the second time, the goal is disallowed. Offside.
13th minute Van Bommel slides in late on Vieira. Free kick, no card. Vieira goes down again under a Dutch challenge.
Hope Cygancan step up also talksport.net is doing commentary of the CL and goes to the pitches every few minutes and whenever their is a goal.